diff --git a/biblio.bib b/biblio.bib index 440158d..950df3d 100644 --- a/biblio.bib +++ b/biblio.bib @@ -655,3 +655,18 @@ @article{jiAirStableOrganicRadicals2020 file = {/home/pierre/Zotero/storage/8GRINQS5/Ji et al. - 2020 - Air-Stable Organic Radicals New-Generation Materi.pdf;/home/pierre/Zotero/storage/I6ZDH48P/adma.html} } +@article{hanschSurveyHammettSubstituent1991, + title = {A Survey of {{Hammett}} Substituent Constants and Resonance and Field Parameters}, + author = {Hansch, {\relax Corwin}. and Leo, A. and Taft, R. W.}, + year = {1991}, + month = mar, + journal = {Chemical Reviews}, + volume = {91}, + number = {2}, + pages = {165--195}, + publisher = {American Chemical Society}, + issn = {0009-2665}, + doi = {10.1021/cr00002a004}, + urldate = {2024-05-24}, + file = {/home/pierre/Zotero/storage/5HQ2AU8W/Hansch et al. - 1991 - A survey of Hammett substituent constants and reso.pdf} +} diff --git a/nitroxides_SI.tex b/nitroxides_SI.tex index 2e3edea..8b6542a 100644 --- a/nitroxides_SI.tex +++ b/nitroxides_SI.tex @@ -135,8 +135,23 @@ \begin{figure}[!h] \centering + \begin{tblr}{lcc} + \hline + & $\sigma_p$ & $\sigma_m$ \\ + \hline + \ce{COOH} & 0.45 &0.37 \\ + \ce{NH2} & -0.66 & -0.16 \\ + \ce{OMe} & -0.27 & 0.12 \\ + \ce{OH} & -0.37 & 0.12 \\ + \ce{NH3+} & 0.60 & 0.86 \\ + \ce{Br} & 0.23 & 0.39 \\ + $>$\ce{C=O} & 0.50 & --- \\ + \ce{C=C-CONH2} & 0.36 & 0.28 \\ + \ce{NO2} & 0.78 & 0.71 \\ + \hline + \end{tblr} \includegraphics [width=\linewidth]{FigureS4} - \caption{Correlation between absolute oxidation (left) and reduction (right) and the Hammet constant of their substituent for compounds of the P5O (black markers) and P6O (blue markers) families.} + \caption{Correlation between absolute oxidation (left) and reduction (right) and the Hammet constant of their substituent (para, $\sigma_p$, or meta, $\sigma_m$, from Ref.~\cite{hanschSurveyHammettSubstituent1991} and reported in the table) for compounds of the P5O (black markers, correlated with $\sigma_m$) and P6O (blue markers, with correlated with $\sigma_p$) families.} \end{figure} \clearpage