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add Hammet constants
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pierre-24 committed Jun 3, 2024
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15 changes: 15 additions & 0 deletions biblio.bib
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Expand Up @@ -655,3 +655,18 @@ @article{jiAirStableOrganicRadicals2020
file = {/home/pierre/Zotero/storage/8GRINQS5/Ji et al. - 2020 - Air-Stable Organic Radicals New-Generation Materi.pdf;/home/pierre/Zotero/storage/I6ZDH48P/adma.html}
}

@article{hanschSurveyHammettSubstituent1991,
title = {A Survey of {{Hammett}} Substituent Constants and Resonance and Field Parameters},
author = {Hansch, {\relax Corwin}. and Leo, A. and Taft, R. W.},
year = {1991},
month = mar,
journal = {Chemical Reviews},
volume = {91},
number = {2},
pages = {165--195},
publisher = {American Chemical Society},
issn = {0009-2665},
doi = {10.1021/cr00002a004},
urldate = {2024-05-24},
file = {/home/pierre/Zotero/storage/5HQ2AU8W/Hansch et al. - 1991 - A survey of Hammett substituent constants and reso.pdf}
}
17 changes: 16 additions & 1 deletion nitroxides_SI.tex
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Expand Up @@ -135,8 +135,23 @@

\begin{figure}[!h]
\centering
\begin{tblr}{lcc}
\hline
& $\sigma_p$ & $\sigma_m$ \\
\hline
\ce{COOH} & 0.45 &0.37 \\
\ce{NH2} & -0.66 & -0.16 \\
\ce{OMe} & -0.27 & 0.12 \\
\ce{OH} & -0.37 & 0.12 \\
\ce{NH3+} & 0.60 & 0.86 \\
\ce{Br} & 0.23 & 0.39 \\
$>$\ce{C=O} & 0.50 & --- \\
\ce{C=C-CONH2} & 0.36 & 0.28 \\
\ce{NO2} & 0.78 & 0.71 \\
\hline
\end{tblr}
\includegraphics [width=\linewidth]{FigureS4}
\caption{Correlation between absolute oxidation (left) and reduction (right) and the Hammet constant of their substituent for compounds of the P5O (black markers) and P6O (blue markers) families.}
\caption{Correlation between absolute oxidation (left) and reduction (right) and the Hammet constant of their substituent (para, $\sigma_p$, or meta, $\sigma_m$, from Ref.~\cite{hanschSurveyHammettSubstituent1991} and reported in the table) for compounds of the P5O (black markers, correlated with $\sigma_m$) and P6O (blue markers, with correlated with $\sigma_p$) families.}
\end{figure}

\clearpage
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